Thermal and Thermo-oxidative Degradations of Polyvinyl Alcohol with 2,5-Furandicarboxylic Acid Acting as A Crosslinking
Main Article Content
Abstract
This study assesses the thermal and thermo-oxidative for PVA with 2,5-furandicarboxylic acid (FDCA) acting as a crosslinking. PVA-crosslinked-FDCA were synthesized via catalyst-free solid-state esterification at 120 °C. PVA and FDCA with different contents of inorganic phase (1, 5, and 10 % (w/w)) were characterized by Attenuated Total Reflection-Fourier Transform Infrared Spectroscopy. The thermal degradation of the obtained products was studied by Thermal Gravimetric Analysis/ Differential Thermal Gravimetric Analysis under air and nitrogen atmosphere. The effect of FDCA content on thermal and thermo-oxidative stability of PVA was discussed. The thermal stability of PVA was significantly improved, particularly at low FDCA concentrations of 1% and 5%. In these cases, the degradation maximums occurred at 361°C and 375°C, respectively, compared to 300°C for unmodified PVA in a nitrogen atmosphere. Moreover, the degradation maximums occurred at 363°C and 399°C, respectively, compared to 337°C for unmodified PVA in an air atmosphere. In addition, thermal stability of the films under air is even better than that under nitrogen atmosphere.
Keywords
Poly(vinyl alcohol), 2,5-furandicarboxylic acid, crosslinking
Article Details
References
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[7] Y. Su, H. M. Brown, X. Huang, X.-d. Zhou, J. E. Amonette, and Z. C. Zhang, Single-step conversion of cellulose to 5-hydroxymethylfurfural (HMF), a versatile platform chemical, Applied Catalysis A: General, vol. 361, no. 1-2, pp. 117-122, 2009. https://doi.org/10.1016/j.apcata.2009.04.002
[8] L. H. Huang, X. Yang, and J. Gao, Study on microstructure effect of carbon black particles in filled rubber composites, International Journal of Polymer Science, vol. 2018, 2018. https://doi.org/10.1155/2018/2713291
[9] N. Vu Trung et al., Tuning the thermal and mechanical properties of poly (vinyl alcohol) with 2, 5-furandicarboxylic acid acting as a biobased crosslinking agent, Polymer Journal, vol. 54, no. 3, pp. 335-343, 2022. https://doi.org/10.1038/s41428-021-00583-y
[10] D. Salgado‐Chavarría and J. Palacios‐Alquisira, Poly (vinyl alcohol) membranes cross‐linked with maleic anhydride and 2, 5‐furandicarboxylic acid: conventional heating and microwave irradiation, ChemistrySelect, vol. 5, no. 16, pp. 4826-4838, 2020. https://doi.org/10.1002/slct.202000564
[11] Z. Peng and L. X. Kong, A thermal degradation mechanism of polyvinyl alcohol/silica nanocomposites, Polymer Degradation Stability, vol. 92, no. 6, pp. 1061-1071, 2007. https://doi.org/10.1016/j.polymdegradstab.2007.02.011
[12] V. Tsanaktsis, E. Vouvoudi, G. Z. Papageorgiou, D. G. Papageorgiou, K. Chrissafis, and D. N. Bikiaris, Thermal degradation kinetics and decomposition mechanism of polyesters based on 2, 5-furandicarboxylic acid and low molecular weight aliphatic diols, Journal of Analytical Applied Pyrolysis, vol. 112, pp. 369-378, 2015. https://doi.org/10.1016/j.jaap.2014.12.016
[13] K. Cao et al., Preparation and properties of an aromatic polyamide fibre derived from a bio-based furan acid chloride, High Performance Polymers, vol. 33, no. 9, pp. 1083-1092, 2021. https://doi.org/10.1177/09540083211020814
[14] K. Cao et al., The preparation and characterization of a heterocyclic meta-aramid fiber with outstanding thermal stability, High Performance Polymers, vol. 33, no. 5, pp. 554-567, 2021. https://doi.org/10.1177/0954008320974415