Effect of Key Parameters on Heterogeneous Fenton-like Oxidation of Indigo carmine catalyzed by Fe2V4O13
Main Article Content
Abstract
In this study, Fe2V4O13 nanoparticle (FeV2) as a hetero-Fenton catalyst was synthesized using a low-temperature hydrothermal method and characterized by X-ray, SEM, EDX, TEM and Raman techniques. The effectiveness of the heterogeneous Fenton catalyst of FeV2 towards the degradation and mineralization of indigo carmine dye (Ind, 0.1 mM) was studied by UV-Vis, ICP-MS and COD measurement. The optimal conditions for maximum degradation were pH 4, 66.7 mg/L of Fe2V4O13, 0.3 mM of initial H2O2 concentration with 0.1 mM of initial Ind concentration, at a reaction temperature of 298 K. The effect of temperature on the reaction was also investigated, resulting in the activation energy of the reaction Ea = 53.5 kJ mol⁻¹. Using the Eyring equation, activated parameters were calculated, indicating the controlling parameter is the activated enthalpy, the step of activated complex formation is an associative and endothermic reaction. It also performed that the FeV2 catalyst was highly influential in the degradation and mineralization of indigo carmine dye, with a degradation efficiency of more than 90% and 85% of COD after 10 minutes under the optimal operating condition. Additionally, the FeV2 catalyst displayed good stability after four cycles, indicating that Fe2V4O13 could be a promising catalyst for treating textile dye wastewater containing indigo carmine.
Keywords
heterogeneous Fenton-like system, hydroxyl radical, Indigo carmine, textile dyes, wastewater
Article Details
References
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[17] G. Ye, J. Zhou, R. Huang, Y. Ke, Y. Peng, Y. Zhou, Y. Weng, C. Ling, W. Pan, Magnetic sludge-based biochar derived from Fenton sludge as an efficient heterogeneous Fenton catalyst for degrading Methylene blue, J. Environ. Chem. Eng., Vol 10, no. 2, 2022, pp. 107242. https://doi.org/10.1016/j.jece.2022.107242
[2] M. F. Chowdhury, S. Khandaker, F. Sarker, A. Islam, M. T. Rahman, and M. R. Awual, Current treatment technologies and mechanisms for removal of indigo carmine dyes from wastewater: A review, J. Mol. Liq., vol 318, Nov. 2020, pp. 114061. https://doi.org/10.1016/j.molliq.2020.114061
[3] M. A. Oturan and J. J. Aaron, Advanced oxidation processes in water/wastewater treatment: principles and applications. A review. Critical Reviews in Environmental Science and Technology, vol 44, no 23, Dec. 2014, pp. 2577-2641. https://doi.org/10.1080/10643389.2013.829765
[4] N. Thomas, D. D. Dionysiou, and S. C. Pillai, Heterogeneous Fenton catalysts: A review of recent advances. J. Hazard. Mater., vol 404, Feb.2021, pp. 124082. https://doi.org/10.1016/j.jhazmat.2020.124082
[5] J. P. Ribeiro and M. I. Nunes, Recent trends and developments in Fenton processes for industrial wastewater treatment - A critical review, Environ. Res., vol 197, pp. 110957, Jun. 2021. https://doi.org/10.1016/j.envres.2021.110957
[6] M. Azfar Shaida, S. Verma, S. Talukdar, N. Kumar, M. Salim Mahtab, M. Naushad, and I. Haq Farooqi, Critical analysis of the role of various iron-based heterogeneous catalysts for advanced oxidation processes: A state of the art review. J. Mol. Liq., vol 374, Mar. 2023, pp. 121259. https://doi.org/10.1016/j.molliq.2023.121259
[7] J. Wang and J. Tang, Fe-based Fenton-like catalysts for water treatment: Catalytic mechanisms and applications, J. Mol. Liq., vol. 332, Jun. 2021, p. 115755. https://doi.org/10.1016/j.molliq.2021.115755
[8] Y.-Y. Zhang, C. He, J.-H. Deng, Y.-T. Tu, J.-K. Liu, and Y. Xiong, Photo-Fenton-like catalytic activity of nanolamellar Fe2V4O13 in the degradation of organic pollutants, Res. Chem. Intermed., vol. 35, no. 6 Dec. 2009, p. 727. https://doi.org/10.1007/s11164-009-0090-0
[9] L. Lai, H. Ji, H. Zhang, R. Liu, C. Zhou, W. Liu, Z. Ao, N. Li, C. Liu, G. Yao, and B. Lai, Activation of peroxydisulfate by V-Fe concentrate ore for enhanced degradation of carbamazepine: Surface ≡V(III) and ≡V(IV) as electron donors promoted the regeneration of ≡Fe(II). Appl. Catal. B, vol 282, Mar. 2021, pp. 119559. https://doi.org/10.1016/j.apcatb.2020.119559
[10] P. S. Adarakatti, M. Mahanthappa, E. H, and A. Siddaramanna, Fe2V4O13 nanoparticles based electrochemical sensor for the simultaneous determination of guanine and adenine at nanomolar concentration. Electroanalysis, vol 30, no. 9, Sep. 2018, pp. 1971-1982. https://doi.org/10.1002/elan.201800124
[11] S. Marikkani, J. V. Kumar, and V. Muthuraj, Design of novel solar-light driven sponge-like Fe2V4O13 photocatalyst: A unique platform for the photoreduction of carcinogenic hexavalent chromium. Sol. Energy, vol 188, Jun. 2019, pp. 849-856. https://doi.org/10.1016/j.solener.2019.06.075
[12] K. Gowthami et al., Fe2V4O13 assisted hetero-Fenton mineralization of methyl orange under UV-A light irradiation, Iran. Chem. Com., Vol 6, no. 1, no. 18, Jan. 2018, pp. 97-108.
[13] N. D. V. Manh, N. Vân-Anh, B. B. Canh, N. H. Lien, P. T. T. Nga, C. H. Ha, Hydrothermal synthesis and catalytic activity of a nanosized Fe2V4O13 material in heterogeneous fenton-like reaction for degradation of organic compounds, Vietnam Journal of Catalysis and Adsorption, vol. 12, no. 2, Jun. 2023, p. 5. https://doi.org/10.51316/jca.2023.024
[14] ISO 6060:1989 Water quality - Determination of the Chemical Oxygen Demand International Organization for Standardization, Geneva, Switzerland. 1989.
[15] Y. Wang, W. Li, and A. Irini, A novel and quick method to avoid H2O2 interference on COD measurement in Fenton system by Na2SO3 reduction and O2 oxidation, Water Sci. Technol., vol. 68, no. 7, 2013, pp. 1529-1535. https://doi.org/10.2166/wst.2013.396
[16] M. R. da Silva Pelissari, L. P. Camargo, P. R. C. da Silva, and L. H. Dall’Antonia, Fe2V4O13 photoanode material: an interesting approach to non-enzymatic glucose oxidation, J. Mater. Sci., vol 57, no. 14, 2022, pp. 7173-7190. https://doi.org/10.1007/s10853-022-07093-z
[17] G. Ye, J. Zhou, R. Huang, Y. Ke, Y. Peng, Y. Zhou, Y. Weng, C. Ling, W. Pan, Magnetic sludge-based biochar derived from Fenton sludge as an efficient heterogeneous Fenton catalyst for degrading Methylene blue, J. Environ. Chem. Eng., Vol 10, no. 2, 2022, pp. 107242. https://doi.org/10.1016/j.jece.2022.107242