Synthesis and Electrochemical Characterization of Graphene/Poly(1,8-diaminonaphthalene) Nanocomposite Films
Main Article Content
Abstract
Graphene (Gr) was introduced as a great promise for various applications due to its enhanced electrical properties. Therefore, Gr would be a potential functional component to prepare conducting polymer composites with superior material properties. This study reports the preparation of a graphene/poly(1,8-diaminonaphthalene) composite material on a glassy carbon electrode by electrochemical technique. The electrochemical behaviours recorded by cyclic voltammetry and electrochemical impedance spectroscopy techniques clearly indicated that the synthesized composite films were much more electroactive and more stable than the pure poly(1,8-diaminonaphthalene) film. From the experimental data in this work, the label-free electrochemical sensors based on graphene/poly(1,8-diaminonaphthalene) could be developed by enhancing the intrinsic electrical properties of the composite material.
Keywords
graphen, poly (1,8-diaminonaphtalen), conductive polymer
Article Details
References
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[6]. N.V. Chuc, N.H. Binh, C.T. Thanh, N.V. Tu, N.L. Huy, N.T. Dung, P.N. Minh, V.T. Thu, T.D. Lam, Electrochemical Immunosensor for Detection of Atrazine Based on Polyaniline/Graphene, J. Mater. Sci. Technol. 32 (2016) 539-544.
[7]. M. El Rhazi, S. Majid, Electrochemical sensors based on polydiaminonaphthalene and polyphenylenediamine for monitoring metal pollutants, Trends Environ. Anal. Chem. 2 (2014) 33-42.
[8]. V.A. Nguyen, H.L. Nguyen, D.T. Nguyen, Q.P. Do, L.D. Tran, Electrosynthesized Poly(1,5-diaminonaphthalene)/polypyrrole nanowires bilayer as an immunosensor platform for breast cancer biomarker CA 15-3, Curr. Appl. Phys. 17 (2017) 1422-1429.
[9]. M. Tagowska, B. Palys, M. Mazur, M. Skompska, K. Jackowska, In situ deposition of poly(1,8-diaminonaphthalene): from thin films to nanometer-sized structures, Electrochim. Acta 50 (2005) 2363-2370.
[10]. N.T. Dung, P.N. Bách, Đ.I. Anh, T.T.X. Hằng, Tổng hợp điện hóa màng poly(1,8-diaminonaphtalen) trong môi trường nước. Tạp chí Khoa học và Công nghệ, 46 (2008) 97-101.
[11]. J. Shi, J.C. Claussen, E.S. McLamore, A. ul Haque, D. Jaroch, A.R. Diggs, P. Calvo-Marzal, J.L. Rickus, D.M. Porterfield, A comparative study of enzyme immobilization strategies for multi-walled carbon nanotube glucose biosensors, Nanotechno., 22 (2011) 355502.
[12]. M.P. Siswana, K.I. Ozoemena, T. Nyokong, Electrocatalysis of asulam on cobalt phthalocyanine modified multi-walled carbon nanotubes immobilized on a basal plane pyrolytic graphite electrode, Electrochim. Acta. 52 (2006) 114-122.