Study on Fabrication of Catalyst Based on Minerals of Tuyen Quang for Ozonization of Pulp Mill's Effluents

Tien Dung Bui1, Duy Hoang Doan2, Quang Dien Le3, Huy Hoang Phan3,
1 Chemical Company 21, Phu Tho
2 Viet Tri University of Industry, No. 9, Tien Son Street, Viet Tri
3 Hanoi University of Science and Technology - No. 1, Dai Co Viet, Hai Ba Trung, Hanoi

Main Article Content

Abstract

This study presented the fabrication of catalyst from iron ore of Tuyen Quang and application for ozonization of pulp mill's effluents. Iron ore was treated, refined and screened to obtain the particles with suitable size. The pretreated ore was subjected to fabricate the catalyst by oxidation at different conditions. Furthermore, the process for making of catalyst tablet was also studied to achieve the particles with big size for industrial catalyst. As-obtained catalyst was investigated in ozonization of An Hoa pulp mill's effluents to reduce the effluent colour. The results showed that catalyst from mineral of Tuyen Quang exhibited the high catalytic efficiency in reduction of colour of pulp mill's effluents. By ozonization with catalyst dosage of 5 mg/l, the colour degree of effluents was reduced by 60%. The pulp mill's effluents after treatment had the acceptable colour degree as Vietnam Standard on Environment.

Article Details

References

[1] Tạp chí địa chất số 6 (1962), “Đặc điểm các loại mô quặng sắt ở Thái Nguyên, Tuyên Quang. Cao Bằng, Bắc Cạn".
[2] Lê Quang Diễn, “Công nghệ sản xuất bột giấy”, NXB Bách Khoa, Hà Nội (2015).
[3] Lawrence K. Wang. Yung-Tse Hung, Howard H.Lo, Constantine Yapijiakis, Waste Treatment in the Process Industries, Taylor & Francis Group, LLC, 2006.
[4] Wu, C.H., Kuo, C.Y., Chang, C.L., Homogeneous catalytic ozonation of C.I. Reactive Red 2 by metallic ions in a bubble column reactor. Journal of Hazardous Materials, 2008, 154, 748-755.
[5] Beltrán, F.J., Rivas, F.J., Montero-de-Espinosa, R., Iron type catalysts for the ozonation of oxalic acid in water. Water Research, 2005, 39, 3553-3564.