Robust Multi-objective Optimization of Peanut Shell Biochar Production under Uncertainty Using Gaussian Process and NSGA-II
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Abstract
As fossil fuels continue to dominate the global energy mix, the thermochemical conversion of biomass via pyrolysis offers a carbon-neutral pathway to produce high-value biochar. However, optimizing this highly nonlinear process remains challenging, especially when constrained by limited experimental data. This study investigates the pyrolysis of peanut shell—an abundant agricultural residue in ASEAN countries—aiming to simultaneously maximize biochar yield and fixed carbon content. To overcome the small dataset limitation (N = 9), a Gaussian Process Regression (GPR) model was developed. Incorporating Leave-One-Out Cross-Validation (LOOCV) and hyperparameter tuning, the GPR approach effectively mitigated overfitting while providing intrinsic uncertainty quantification—a distinct advantage over conventional machine learning methods. The surrogate model demonstrated high predictive accuracy (R2 = 0.9975 for yield and 0.9341 for fixed carbon). By coupling GPR with the NSGA-II algorithm, a robust multi-objective optimization framework was established. The generated Pareto front identified optimal operating conditions that secured high fixed carbon levels (e.g., > 75 wt%) while maintaining total predictive uncertainty below 2.5%. Ultimately, this data-efficient framework provides a highly reliable strategy for optimizing biomass pyrolysis and scaling sustainable bioenergy systems with minimal experimental overhead.
Keywords
Biomass pyrolysis, Biochar yield, Gaussian Process Regression, NSGA-II, Uncertainty quantification.
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