Synthesis of Zeolitic - Imidazolate Framework – 67 in Ethanol by Using Ultrasonication
Main Article Content
Abstract
The ZIF-67 nanocrystal was successfully synthesized in ethanol as solvent by using ultrasound with shorter synthesis time as compared to solvo-thermal method. The synthesized ZIF-67 crystals were characterized by XRD, SEM, TEM, FT-IR, N2 adsorption-desorption and TGA/DTA. It was found that the ZIF-67 crystals were highly stable up to 350°C (in air), and have shown high crystallinity with a uniform crystallite size of around 50 nm (TEM), BET surface area of 1363 m²/g and Langmuir surface area of 1912 m²/g. Methylene blue absorption and photocatalysis of ZIF-67 nano-material were investigated. The results indicated the material is capable to promote photocatalysis to treat methylene blue; furthermore, the effect was enhanced with the addition of H₂O₂.
Keywords
MOFs, ZIF-67, ethanol, rung siêu âm, xúc tác quang
Article Details
References
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[3] K.Yi A. Lin, H.A. Chang, Ultra-high adsorption capacity of zeolitic imidazole framework-67 (ZIF-67) for removal of malachite green from water, Chemosphere, 139 (2015) 624-631.
[4] E. A. Garcia, L. O. Arteta, J. Gascon, and F. Kapteijn, ZIF-67 as silver-bullet in adsorptive propane/propylene separation, Chem. Eng. J. (2019) 10–14.
[5] C. Chu, S. Rao, Z. Ma, and H. Han, Copper and cobalt nanoparticles doped nitrogen-containing carbon frameworks derived from CuO-encapsulated ZIF-67 as high-efficiency catalyst for hydrogenation of 4-nitrophenol, Appl. Catal. B Environ., vol. 256 (2019) 117792.
[6] H.Yang, X.W. He, F. Wang, Y. Kang and J. Zhang, Doping copper into ZIF-67 for enhancing gas uptake capacity and visible-light-driven photocatalytic degradation of organic dye, J. Mater. Chem., 22(41) (2012) 21849-21851.
[7] H. Park, D. A. Reddy, Y.Kim, R. Ma, J. Choi, T. K. Kim, K.S. Lee, Zeolitic imidazolate framework-67 (ZIF-67) rhombic dodecahedrons as full-spectrum light harvesting photocatalyst for environmental remediation, Solid State Sciences 62 (2016) 82-89.
[8] Er-Xia Chen, Hui Yang, Jian Zhang, Zeolitic Imidazolate Framework as Formaldehyde Gas Sensor, Inorg. Chem, 53 (2014) 5411−5413
[9] J. Qian, F. Sun, L. Qin, Hydrothermal synthesis of zeolitic imidazolate framework-67 (ZIF-67) nanocrystals, Materials Letters. 82 (2012) 220–223.
[10] J. Qin, S. Wang, and X. Wang, Visible-light reduction CO2 with dodecahedral zeolitic imidazolate framework ZIF-67 as an efficient co-catalyst, Appl. Catal. B Environ., vol. 209 (2017) 476–482.
[11] N. T.T. Tu , P. C. Sy , T.V. Thien , T. T.T. Toan, N. H. Phong, H. T. Long, and D. Q. Khieu, Microwave-assisted synthesis and simultaneous electrochemical determination of dopamine and paracetamol using ZIF-67-modified electrode, J Mater Sci (2019) 54:11654–11670.
[12] L.V. Dương, Đ.Q. Toàn, P.T. Hương, L.N. Dương, N.T. Xuân, N.T. Phương, T.N. Đôn, Study on preparation of nano-ZIF-67 in ethanol, Vietnam Journal of Catalysis and Adsorption, 7(1) (2018) 123-128.
[13] H. Zhang, J. Zhong, G. Zhou, J. Wu, Z. Yang, and X.hi, Microwave-Assisted Solvent-Free Synthesis of Zeolitic Imidazolate Framework-67, Journal of Nanomaterials (2016)1-9.
[14] Guo, X., Xing, T., Lou, Y., and Chen, J., Controlling ZIF-67 crystals formation through various cobalt sources in aqueous solution. Journal of Solid State Chemistry. 235(1) (2016) 107-112.
[15] J. Y. Lee and W. K. Jo, Application of ultrasound-aided method for the synthesis of CdS-incorporated three-dimensional TiO2 photocatalysts with enhanced performance, Ultrason. Sonochem., vol. 35 (2017) 440–448.
[16] Jordan J. Hinman, Kenneth S. Suslick, Nanostructured Materials Synthesis Using Ultrasound, Top Curr Chem (Z) (2017) 375:12.
[17] M. Ammar, S. Jiang, and S. Ji, Heteropoly acid encapsulated into zeolite imidazolate framework (ZIF-67) cage as an efficient heterogeneous catalyst for Friedel–Crafts acylation, J. Solid State Chem., vol. 233 (2016) 303–310.
[18] X. Kang, Z.W. Song, Q.Shi and J.X. Dong, Utilization of Zeolite Imidazolate Framework as an Adsorbent for the Removal of Dye from Aqueous Solution, Asian Journal of Chemistry; Vol. 25, No. 15 (2013), 8324-8328.
[19] J. Dou, D. Li, H. Li, Q. Kang, J. Lu, D.Shen, A differential photoelectrochemical hydrogen peroxide sensor based on catalytic activity difference between two zeolitic imidazolate framework surface coatings, Talanta 197 (2019) 138–144.
[20] R. Guan, J.Li, J. Zhang, Z. Zhao, D. Wang, H. Zhai and D. Sun, Photocatalytic Performance and Mechanistic Research of ZnO/g-C3N4 on Degradation of Methyl Orange, ACS Omega, 4 (2019) 20742−20747.