Influence of Structure on Catalytic Properties of La0.7Sr0.3BO3 (B = Mn, Fe, Ni) Perovskite Catalysts in Total Oxidation Reaction of M-Xylene
Main Article Content
Abstract
The perovskite - type complex oxides of La¬0.7Sr0.3BO3 (B = Mn, Fe, Ni) were prepared, studied of catalytic activity and kinetic in total oxidation reaction of m-xylen in our previous reports. Results showed that perovskite phases can be perfectly crystallized at the temperature of 600oC and they have good catalytic activity and low activation energy in total oxidation reaction of m-xylen. The reaction of total oxidation of m- xylene on the La¬0.7Sr0.3BO3 (B = Mn, Fe, Ni) catalysts occurs mainly in the low temperature range (200-300oC ), so the amount of adsorbent oxygen on the catalyst is an important factor affecting the catalytic properties of this material system. In this report, we continue studying the influence of structure on catalytic properties of La¬0.7Sr0.3BO3 (B = Mn, Fe, Ni) catalysts in total oxidation reaction of m-xylen based on the measurable results of crystal structure analysis by Rietveld analysis method, infra-red spectroscopy and temperature - programmed desorption of oxygen. Obtained results show that between structure and catalytic properties of catalyst have a close relationship: the more structural distortion in perovskit occurs, the greater of the amount of adsorbent oxygen and the link B-O of catalysts is the less durable, the higher of catalytic activity in total oxidation recation of m-xylene.
Keywords
catalyst, perovskite, oxidation, m-xylene
Article Details
References
[1] Wenjun Zhu, Xiao Chen, Zhongmin Liu, Changhai Liang, Insight into the effect of cobalt substitution on the catalytic ferformance of LaMnO3 perovskites for total oxidation of propane, The Journal of Physical Chemistry, 124 (27), (2020) 14646-14657, https://doi.org/10.1021/acs.jpcc.0c03084
[2] Ngô Thị Thuận, Nguyễn Thế Hữu, Oxi hóa chọn lọc toluen trong pha lỏng trên xúc tác LaFe0,7Cu0,3O3, Tạp chí Hóa Học, T.47 (2A), (2009) 25-28,
[3] Ji Yang, Siyu Hu, Yarong Fang, Son Hoang, Li Li, Weiwei Yang, Zhenfeng Liang, Jian Wu, Jinpeng Hu, Wen Xiao, Chuanqi Pan, Zhu Luo, Jun Ding, Lizhi Zhang, Yanbing Guo, Oxygen vacancy promoted O2 activation over perovskite oxide for low-temperature CO oxidation, ACS Catalysis, 9 (11), (2019) 9751-9763, https://doi.org/10.1021/acscatal.9b02408
[4] Xiyang Wang, Keke Huang, Long Yuan Yuan, Shibo Xi, Wensheng Yan, Zhibin Geng, Yingge Cong, Yu Sun, Hao Tan, Xiaofeng Wu, Liping Li, and Shouhua Feng, Activation of surface oxygen sites in a cobaltbased perovskite model catalyst for CO oxidation, The Journal of Physical Chemistry Letters, 9 (15), (2018) 4146-4154, https://doi.org/10.1021/acs.jpclett.8b01623
[5] Jianping Yang, Mingguang Zhang, Hailong Li, Wenqi Qu, Yongchun Zhao, and Junyning Zhang, Simultaneous NO reduction and Hg0 oxidation over La0.8Ce0.2MnO3 perovskite catalysts at low temperature, Industrial & Engineering Chemistry Research, 57 (29), (2018) 9374-9385, https://doi.org/10.1021/acs.iecr.8b01431
[6] Lê.T.H.T, Nghiên cứu chế tạo và tính chất quang xúc tác của một số vật liệu perovskit Bi05A0,5TiO3 nhằm ứng dụng xử lý môi trường, Luận án Tiến sĩ, ĐHQG Hà Nội (2020),
[7] Jonathan Hwang, Reshma R. Rao, Livia Giordano, Yu Katayama, Yang Yu, Yang Shao - Horn, Perovskite in catalysis and electrocatalysis, Science 10, Vol.358, (2017) 751-756, https://doi.org/10.1126/science.aam7092
[8] Mi Young Oh, Jung Hyun Kim, Young Wook Lee, Kyeong Joon Kim, Hong Rim Shin, Hyeokjun Park, Kang Taek Lee, Kisuka Kang, and Tae Ho Shin, Enhancing bifunctional catalytic activity via a nanostructured La(Sr)Fe(Co)O3−δ matrix as an efficient electrocatalyst for Li-O2 batteries, ACS Applied Energy Materials, 2 (12), (2019) 8633-8640. https://doi.org/10.1021/acsaem.9b01540
[9] Trần Thị Thu Huyền, Trần Thị Luyến, Nguyễn Thị Minh Hiền, Nguyễn Hữu Phú, Tổng hợp, đặc trưng và tính chất xúc tác của các perovskit La0,7Sr0,3BO3 (B = Mn, Fe, Ni), Tạp chí Hóa Học, T.47 (2A), (2009) 14-18,
[10] Trần Thị Thu Huyền, Trần Thị Luyến, Nguyễn Thị Tuyết Mai, Xác định năng lượng hoạt hóa của phản ứng oxi hóa hoàn toàn m-xylen trên các xúc tác perovskit La0,7Sr0,3BO3 (B = Mn, Fe, Ni), Tạp chí Khoa học ĐHQG Hà Nội: Khoa học Tự nhiên và Công nghệ, T.33 (4), (2017) 79-84,
[11] Penã M.A. and Fierro J.L.G., Chemical structures and performance of perovskite oxide, Chem. Rev., 101, (2001) 1981-2018, https://doi.org/10.1021/cr980129f
[12] Chen Weifan, Li Fengsheng, Liu Leili, Liu Yang, OneStep synthesis of nanocrytalline perovskite LaMnO3 powders via microwave-Induced solution Combustion Route, Rare Earths, 24, (2006) 782-787. https://doi.org/10.1016/S1002-0721(07)60029-5
[13] Manjunath B. Bellakki, V. Manivannan, Jaydip Das, Synthesis, Structural and magnetic properties of La1-xCdxFeO3 (0.0≤x≤0.3) orthoferrites, Mater. Res.Bull, 44, (2009) 1522 – 1527. https://doi.org/10.1016/j.materresbull.2009.02.010
[14] Wang Hong, Zhao Zhen, XU Chunming, Liu Jian, LU Zhixiao, The La 1- xM xMnO 3 (M = Li, Na, K, Rb, x = 0, 0.10, 0.25) Perovskite-type oxides whose sizes are nanoparticle have been prepared by the citric acid-ligated method, Chinese Sci., 50, (2005) 1440-1444,
[15] Tran Thi Minh Nguyet, Nguyen Quang Huan, Nguyen Quoc Trung, Le Van Tiep, Study on the preparation of by sol-gel method and its catalytic activity, The second International Workshop on Nanophysics and Nanotechnology, (2004) 313-316,
[16] Royer S., et al, Methane Oxidation over Nanocrystalline LaCo1-xFexO3: Resistance to SO2 pvisoning, Ind. Eng. Chem. Res, 43, (2004) 5670-5680, https://doi.org/10.1021/ie030775r
[2] Ngô Thị Thuận, Nguyễn Thế Hữu, Oxi hóa chọn lọc toluen trong pha lỏng trên xúc tác LaFe0,7Cu0,3O3, Tạp chí Hóa Học, T.47 (2A), (2009) 25-28,
[3] Ji Yang, Siyu Hu, Yarong Fang, Son Hoang, Li Li, Weiwei Yang, Zhenfeng Liang, Jian Wu, Jinpeng Hu, Wen Xiao, Chuanqi Pan, Zhu Luo, Jun Ding, Lizhi Zhang, Yanbing Guo, Oxygen vacancy promoted O2 activation over perovskite oxide for low-temperature CO oxidation, ACS Catalysis, 9 (11), (2019) 9751-9763, https://doi.org/10.1021/acscatal.9b02408
[4] Xiyang Wang, Keke Huang, Long Yuan Yuan, Shibo Xi, Wensheng Yan, Zhibin Geng, Yingge Cong, Yu Sun, Hao Tan, Xiaofeng Wu, Liping Li, and Shouhua Feng, Activation of surface oxygen sites in a cobaltbased perovskite model catalyst for CO oxidation, The Journal of Physical Chemistry Letters, 9 (15), (2018) 4146-4154, https://doi.org/10.1021/acs.jpclett.8b01623
[5] Jianping Yang, Mingguang Zhang, Hailong Li, Wenqi Qu, Yongchun Zhao, and Junyning Zhang, Simultaneous NO reduction and Hg0 oxidation over La0.8Ce0.2MnO3 perovskite catalysts at low temperature, Industrial & Engineering Chemistry Research, 57 (29), (2018) 9374-9385, https://doi.org/10.1021/acs.iecr.8b01431
[6] Lê.T.H.T, Nghiên cứu chế tạo và tính chất quang xúc tác của một số vật liệu perovskit Bi05A0,5TiO3 nhằm ứng dụng xử lý môi trường, Luận án Tiến sĩ, ĐHQG Hà Nội (2020),
[7] Jonathan Hwang, Reshma R. Rao, Livia Giordano, Yu Katayama, Yang Yu, Yang Shao - Horn, Perovskite in catalysis and electrocatalysis, Science 10, Vol.358, (2017) 751-756, https://doi.org/10.1126/science.aam7092
[8] Mi Young Oh, Jung Hyun Kim, Young Wook Lee, Kyeong Joon Kim, Hong Rim Shin, Hyeokjun Park, Kang Taek Lee, Kisuka Kang, and Tae Ho Shin, Enhancing bifunctional catalytic activity via a nanostructured La(Sr)Fe(Co)O3−δ matrix as an efficient electrocatalyst for Li-O2 batteries, ACS Applied Energy Materials, 2 (12), (2019) 8633-8640. https://doi.org/10.1021/acsaem.9b01540
[9] Trần Thị Thu Huyền, Trần Thị Luyến, Nguyễn Thị Minh Hiền, Nguyễn Hữu Phú, Tổng hợp, đặc trưng và tính chất xúc tác của các perovskit La0,7Sr0,3BO3 (B = Mn, Fe, Ni), Tạp chí Hóa Học, T.47 (2A), (2009) 14-18,
[10] Trần Thị Thu Huyền, Trần Thị Luyến, Nguyễn Thị Tuyết Mai, Xác định năng lượng hoạt hóa của phản ứng oxi hóa hoàn toàn m-xylen trên các xúc tác perovskit La0,7Sr0,3BO3 (B = Mn, Fe, Ni), Tạp chí Khoa học ĐHQG Hà Nội: Khoa học Tự nhiên và Công nghệ, T.33 (4), (2017) 79-84,
[11] Penã M.A. and Fierro J.L.G., Chemical structures and performance of perovskite oxide, Chem. Rev., 101, (2001) 1981-2018, https://doi.org/10.1021/cr980129f
[12] Chen Weifan, Li Fengsheng, Liu Leili, Liu Yang, OneStep synthesis of nanocrytalline perovskite LaMnO3 powders via microwave-Induced solution Combustion Route, Rare Earths, 24, (2006) 782-787. https://doi.org/10.1016/S1002-0721(07)60029-5
[13] Manjunath B. Bellakki, V. Manivannan, Jaydip Das, Synthesis, Structural and magnetic properties of La1-xCdxFeO3 (0.0≤x≤0.3) orthoferrites, Mater. Res.Bull, 44, (2009) 1522 – 1527. https://doi.org/10.1016/j.materresbull.2009.02.010
[14] Wang Hong, Zhao Zhen, XU Chunming, Liu Jian, LU Zhixiao, The La 1- xM xMnO 3 (M = Li, Na, K, Rb, x = 0, 0.10, 0.25) Perovskite-type oxides whose sizes are nanoparticle have been prepared by the citric acid-ligated method, Chinese Sci., 50, (2005) 1440-1444,
[15] Tran Thi Minh Nguyet, Nguyen Quang Huan, Nguyen Quoc Trung, Le Van Tiep, Study on the preparation of by sol-gel method and its catalytic activity, The second International Workshop on Nanophysics and Nanotechnology, (2004) 313-316,
[16] Royer S., et al, Methane Oxidation over Nanocrystalline LaCo1-xFexO3: Resistance to SO2 pvisoning, Ind. Eng. Chem. Res, 43, (2004) 5670-5680, https://doi.org/10.1021/ie030775r