Synthesis of Zero-Valent Iron Nanoparticles on Polyester Non-Woven Fabric Using Green Chemistry Method for Wastewater Treatment in the Textile Dyeing Industry
Main Article Content
Abstract
Wastewater from the dyeing process is causing serious issues for the ecosystem and humans. Zero-valent iron nanoparticles have been proven as a promising material for environmental treatment through numerous previous studies. In this research, green-synthesized zero-valent iron nanoparticles were obtained from the leaf extract of the Cleistocalyx operculatus. These nanoparticles were then applied onto polyester non-woven fabric with alginate coating on the fabric surface. The modified polyester non-woven fabric with alginate and zero-valent iron nanoparticles (PET/Alginate/nZVI), alginate-coated polyester non-woven fabric (PET/Alginate), and the original polyester non-woven fabric (PET) were evaluated for morphology and structure using scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR). The capability of removing the organic dye Rhodamine B was assessed through UV-Vis spectroscopy. The influence of iron dosage, solution concentration, and solution pH on the dye removal capacity of the material was investigated. Results show that the material has been successfully synthesized for high-performance removal of Rhodamine B dye with an efficiency of 98% after 10 minutes of treatment, and it can be reused multiple times with an efficiency of over 70%.
Keywords
Alginate, green synthesis, polyester nonwoven fabric, zero-valent iron nanoparticles
Article Details
References
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[3] C. D. Raman, and S. Kanmani, Textile dye degradation using nano zero valent iron: A review, J. Environ. Manage., vol. 177, pp. 341-355, Jul. 2016. https://doi.org/10.1016/j.jenvman.2016.04.034
[4] N. V. Hoang et al., Green synthesis of zero-valent iron nanoparticles by cleistocalyx operculatus leaf extract using microfluidic device for degradation of the rhodamine B dye. Adv. Nat. Sci: Nanosci. Nanotechnol., vol. 13, no. 4, p. 045007, Nov. 2022. https://doi.org/10.1088/2043-6262/aca023
[5] S. M. Burkinshaw, A. D. Hewitt, R. S. Blackburn, and S. J. Russell, The dyeing of nonwoven fabrics part 1: Initial studies, Dyes. Pigm., vol. 94, no. 3, pp. 592-598, Sep. 2012. https://doi.org/10.1016/j.dyepig.2011.09.011
[6] T. H. Duc et al., Synthesis and application of hydrogel calcium alginate microparticles as a biomaterial to remove heavy metals from aqueous media, Environ. Technol. Innov., vol. 22, p. 101400, May. 2021. https://doi.org/10.1016/j.eti.2021.101400
[7] D. Mihailović et al., Functionalization of polyester fabrics with alginates and TiO2 nanoparticles, Carbohydr. Polym., vol. 79, no. 3, pp. 526-532, Feb. 2010. https://doi.org/10.1016/j.carbpol.2009.08.036
[8] N. Koto and B. Soegijono, Effect of rice husk ash filler of resistance against of high-speed projectile impact on polyester-fiberglass double panel composites, J. Phys.: Conf. Ser., vol. 1191, p. 012058, 2019. https://doi.org/10.1088/1742-6596/1191/1/012058
[9] X. Han et al., Preparation of sepiolite nanofibers supported zero valent iron composite material for catalytic removal of tetracycline in aqueous solution, Front. Chem., vol. 9, p. 736285, Sep 2021. https://doi.org/10.3389/fchem.2021.736285
[10] N. Thi Le et al., Green synthesis of highly stable zero-valent iron nanoparticles for organic dye treatment using Cleistocalyx operculatus leaf extract, Sustain. Chem. Pharm., vol. 25, p. 100598, Apr. 2022. https://doi.org/10.1016/j.scp.2022.100598
[11] P. Qin et al., Highly efficient, rapid, and simultaneous removal of cationic dyes from aqueous solution using monodispersed mesoporous silica nanoparticles as the adsorbent, Nanomaterials, vol. 8, no. 1, p. 4, Dec. 2017. https://doi.org/10.3390/nano8010004